Selectivity of Group VIII Metals for the Catalytic Hydrogenation and Hydrogenolysis of Phenol
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概要
- 論文の詳細を見る
The hydrogenation of phenol has been investigated over group VIII metals by a gas chromatographic pulse technique. Major products were found to be cyclohexanone and cyclohexanol, but benzene, cyclohexane and other hydrocarbons were also formed. The relative amount of cyclohexanol over cyclohexanone formed during the hydrogenation varied by a factor of about 100 depending on both catalyst and reaction temperature. This result was interpreted in terms of the relative catalytic activity of metals for the consecutive reaction : [chemical formula] The initial product due to the breaking of the carbon-oxygen bond was benzene rather than cyclohexane even when cyclohexanol or cyclohexanone was injected in the presence of hydrogen. This unusual result was briefly discussed.
- 社団法人日本薬学会の論文
- 1969-06-25
著者
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山本 晴彦
Faculty Of Pharmaceutical Sciences Hokkaido University
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管 孝男
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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山本 晴彦
Division of Physicochemical Technology, Faculty of Pharmaceutical Sciences, University of Tokyo
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管 孝男
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)faculty Of Pharmaceutical Sc
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