ESR Studies on Bis (O, O'-diethyldithiophosphato) Oxovanadium [IV] in Ether Solutions

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概要

• 論文の詳細を見る

• ESR studies have been made on bis (O, O'-diethyldithiophosphato) oxovanadium [IV], VOdtp_2,in ethyl ether, isopropyl ether, η-butyl ether, and tetrahydrofuran solutions. It has been found that at lower temperatures VOdtp_2 reacts with each of the ethers to form an adduct, VOdtp_2・(R_2O), with structure characterized by the coordination of ether molecule to the equatorial position. The equilibrium constant for the VOdtp_2・(R_2O) formation has also been evaluated ; it increased with increasing basicity of the ether (tetrahydrofuran>ethyl ether>isopropyl ether-n-butyl ether).

• 公益社団法人日本薬学会の論文
• 1974-06-25

著者

• 勝 孝

  岡山大学薬学部

• 勝 孝

  岡山大薬

• 藤田 勇三郎

  Faculty of Pharmaceutical Sciences, Okayama University

• 勝 孝

  Faculty Of Pharmaceutical Sciences Okayama University

• 管 孝男

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 佐藤 三男

  Biophysics Division, Faculty of Pharmaceutical Sciences, Teikyo University

• 佐藤 三男

  Faculty of Pharmaceutical Sciences, The University of Tokyo

• 管 孝男

  Faculty Of Pharmaceutical Sciences The University Of Tokyo

• 佐藤 三男

  Biophysics Division Faculty Of Pharmaceutical Sciences Teikyo University

• 藤田 勇三郎

  Faculty Of Pharmaceutical Sciences Okayama University

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