Application of the Infinite Dilution Shifts in Acid-Base System to Organic Chemistry. I.Relation between the Infinite Dilution Shifts of Monosubstituted Benzoic Acids in Pyridine and the Hammett δ Values
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概要
- 論文の詳細を見る
The relation between the chemical shifts (δ_0) of ortho-, meta-, and para-substituted benzoic acids at infinite dilution in pyridine and the Hammett σ values was investigated. A good linear correlation against σ constants was observed for any of ortho-, meta-, and para-substituted benzoic acids. No correlation has been found up to the present for ortho-substituted benzoic acids by direct method such as the one based upon physical chemistry or NMR, but a good linearity was obtained by the above method.
- 公益社団法人日本薬学会の論文
- 1966-12-25
著者
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近藤 嘉和
Pharmaceutical Inst Institute, Tohoku University
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竹本 常松
Pharmaceutical Institute, Tohoku University
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近藤 一恵
東北大学医学部薬学科
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竹本 常松
Pharmaceutical Faculty Tokushima Bunri University
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池上 恒男
Chemical Research Institute Of Non-aqueous Solutions Tohoku University
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近藤 一恵
Pharmaceutical Institute, Tohoku University School of Medicine
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