Organometallic Compounds. I. Some Transformation Reactions of 1,1'-Diacetylferrocene.
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概要
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Oxidation of 1,1'-diacetylferrocene with sodium hypochlorite and iodine-pyridine gave 1,1-ferrocenedicarboxylic acid (III) and 1-acetyl-1'-ferrocenecarboxylic acid (VI), respectively. The polyester polymer of ferrocene was obtained from dimethyl-1,1'-ferrocenecarboxylate (V) and ethylene glycol. 1,1'-Bis (1-hydroxyethyl) ferrocene (VIII) was converted to 1,1'-(1,1'-epoxydiethyl) ferrocene (IX) by chromatographic method or with p-toluenesulfonyl chloride. Stereochemistry of the cyclic dimethyl ether (IX) is discussed. Treatment of 1,1'-ferrocenedicarboxylic acid with N, N'-dicyclohexylcarbodiimide gave N, N'-dicyclohexyl-N. N' -bis (cyclohexylcarbamoyl) -1,1'-ferrocenedicarboxamide (XIV).
- 公益社団法人日本薬学会の論文
- 1963-07-25
著者
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山川 浩司
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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山川 浩司
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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越智 久雄
昭和大学薬学部
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山川 浩司
Tokyo Research Institute Yawata Iron & Steel Co., Ltd.
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荒川 基一
Tokyo Research Institute Yawata Iron & Steel Co., Ltd.
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越智 久雄
Tokyo Research Institute, Yawata Iron & Steel Co., Ltd.
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