Reduction of β-Keto Sulfoxides Having an Alkyl Group and a Chlorine Atom on the α-Carbon : A Synthesis of (E)-α, β-Epoxy Sulfoxides
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概要
- 論文の詳細を見る
Oxidation of the chlorohydrins derived from 1-chloroalkyl phenyl sulfoxides and aldehydes gave the β-keto sulfoxides having an alkyl group and a chlorine atom on the α-carbon. The β-keto sulfoxides were reduced with diisobutylaluminum hydride to afford the syn-chlorohydrins as sole products, which were converted to the (E)-α, β-epoxy sulfoxides.
- 社団法人日本薬学会の論文
- 1989-01-25
著者
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佐藤 毅
東京理科大学理学部
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佐藤 毅
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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山川 浩司
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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杉本 篤
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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山川 浩司
東京理科大学
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山川 浩司
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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山川 浩司
東京理大
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Satoh T
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Sato Toshiyuki
Yamagata Research Institute Of Technology
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杉本 篤
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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