Organometallic Compounds. V. Gas Chromatographic Analysis of Metal Trifluoroacetylacetonates.

スポンサーリンク

概要

• 論文の詳細を見る

• The separation of various metal trifluoroacetylacetonates is found to be easier than that of acetylacetonate. Although the separation of acetylacetonate of Cr^<3+>, Cu^<2+>, Fe^<3+> and other was found to be not possible due to overlapping, it became possible with trifluoroacetylacetonate. The columns using XE-60,that is nitrile sillicone polymer, as a solid phase liquid gave favorable results. As to those which shows short retention time, the use of Daifl oil, namely Trifluorotrichloroethylene, gave a good chromatogram. In the separation of stereoisomers also XE-60 as well as QF-1 facilitated separation.

• 公益社団法人日本薬学会の論文
• 1967-07-25

著者

• 荒川 基一

  Tokyo Research Institute Yawata Iron & Steel Co., Ltd.

• 谷川 啓一

  Tokyo Research Institute, Yawata Iron & Steel Co., Ltd.

• 荒川 基一

  Tokyo Research Institute Yawata Iron & Steel Co. Ltd.

• 平野 勝美

  Tokyo Research Institute Yawata Iron & Steel Co. Ltd.

• 谷川 啓一

  Tokyo Research Institute, Yawata Iron & Steel Co., Ltd.

関連論文

• Acetylation of Biferrocenyl
• Organometallic Compounds. II. Gas Chromatography of Metal Acetylacetonates.
• Organometallic Compounds. I. Some Transformation Reactions of 1,1'-Diacetylferrocene.
• Organometallic Compounds. V. Gas Chromatographic Analysis of Metal Trifluoroacetylacetonates.
• Organometallic Compounds. IV. Analytical Determination of Ferrocene Derivatives by Gas Chromatography
• ヘキサフルオロアセチルアセトン金属キレートのガスクロマトグラフ法による分析 : 有機金属化合物に関する研究(第6報)
• 有機金属化合物のガスクロマトグラフィー

スポンサーリンク