Application of the Robinson Dehydrogenation Reaction. IV. Oxidation of Some Tetrahydro-β-carboline Derivatives.
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In the course of extensive studies on the Robinson dehydrogenation reaction, 1-(3,4-dihydroxybenzyl)-and 1-(3,4-dihydroxyphenethyl)-1,2,3,4-tetrahydro-β-carbolines (III and VI) and their N-methyl derivatives (V and VII) were oxidized. Though (III) and (V) failed in giving any definite result, (VI) and (VII) gave the same oxidation product (XI), to which was assigned the structure (II) involving additional unsaturation.
- 公益社団法人日本薬学会の論文
- 1959-07-20
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