Photochemical Reaction of Perillaldehyde under Various Conditions
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概要
- 論文の詳細を見る
(-)-Perillaldehyde (1) was photoirradiated by a 400W high-pressure mercury lamp under various conditions. In MeOH, 1 was degraded to give two new MeOH adducts (2 and 3) and a new methyl ether (4) under an N_2 stream, while 1 was converted to a dimethyl acetal (5) and oxidation product (6) in addition to 2 and 3 under an O_2 stream. In EtOAc, 1 disappeared to afford two new dimers (7 and 8) under an N_2 stream, while 1 was changed to two oxygenated products (9 and 10) including a new compound under an O_2 steam. In the presence of rose bengal (RB), 1 was converted to 5 by visible light in MeOH under an N_2 stream. Photosensitizabon of RB was observed under an O_2 steam, and two new oxygenated products (11 and 12) were formed. Perillaldehyde was relatively stable in n-hexane under an N_2 stream or in the presence of RB under an O_2 stream.
- 社団法人日本農芸化学会の論文
- 1992-04-23
著者
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Tada M
Hokkaido Univ. Sapporo Jpn
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Tada Masahiro
Laboratory Of Bio-organic Chemistry Tokyo University Of Agriculture And Technology
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Tada Motohiko
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Tateba Hideki
Ogawa & Co., Ltd.
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Morita Kouzou
Ogawa & Co., Ltd.
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Kameda Wataru
Ogawa & Co., Ltd.
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Tanaka M
Okayama Univ. Okayama Jpn
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Tada M
Graduate School Of Natural Science And Technology Okayama University
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Morita K
Fukuoka Inst. Health And Environmental Sci. Fukuoka Jpn
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Wada Kiriko
Department Of Neurology Hematology Metabolism Endocrinology And Diabetology (dnhmed) Yamagata Univer
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Tateba H
Ogawa & Co. Ltd.
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Kameda Wataru
Department Of Neurology Hematology Metabolism Endocrinology And Diabetology (dnhmed) Yamagata Univer
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Morita K
Univ. Tokyo Tokyo
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Miki Takao
Laboratory Of Bio-organic Chemistry Tokyo University Of Agriculture And Technology
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