Efficient ortho-Oxidation of Phenols with Diacyl Peroxides
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概要
- 論文の詳細を見る
A stable symmetric diacyl peroxide, m-chlorobenzoyl peroxide (mCBPO), and an asymmetric diacyl peroxide, chloroacetyl m-chlorobenzoyl peroxide (CAMCBPO), were synthesized from m-chloroperbenzoic acid. Both peroxides oxidized phenols selectively at the ortho position predoninantly. CAMCBPO gave para-oxidized compounds as minor products from some phenols. The improvement of the yield of ortho-oxidation of phenols with mCBPO was also reported.
- 公益社団法人日本薬学会の論文
- 2008-03-01
著者
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Tada Masahiro
Laboratory Of Bio-organic Chemistry Tokyo University Of Agriculture And Technology
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Tada Masahiro
Laboratory Of Bioorganic Chemistry Tokyo University Of Agriculture And Technology
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Izumi Ryohei
Laboratory Of Bioorganic Chemistry Tokyo University Of Agriculture And Technology
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ISHIGURO Risa
Laboratory of Bioorganic Chemistry, Tokyo University of Agriculture and Technology
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Ishiguro Risa
Laboratory Of Bioorganic Chemistry Tokyo University Of Agriculture And Technology
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