Structure-Odor Relationships in Monoterpenelactones(Organic Chemistry)
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Twelve γ-, δ- and ε-monoterpenelactones were synthesized, with seven compounds (5, 6, 7, 8, 13, 13', and 15) being newly formed. The odor of the monoterpenelactones was found to be dependent on the size of their rings and their conformation. Substitution of the equatorial methyl group at C(3) in the δ- and ε-monoterpenelactones with a planar molecular shape was necessary for the mono-terpenelactones to produce a pronounced maple-like odor.
- 社団法人日本農芸化学会の論文
- 1990-09-23
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