Facile Synthesis of 2-Hydroxy-6-methylbenzaldehyde, an Alarm and Sex Pheromone Component of Astigmatid Mites
スポンサーリンク
概要
- 論文の詳細を見る
2-Hydroxy-6-methylbenzaldehyde (5) is a component of astigmatid mites, functioning as the alarm and sex pheromones, and the establishment of its convenient synthesis is prerequisite and of vital importance to develop applications of these pheromones for practical use. The target compound (5) was effectively synthesized from m-cresol (1) by the following four steps in a 44% overall yield: protection of the hydroxyl group by a tetrahydropyranyl group, blocking the active site (6-position of 1) by a trimethylsilyl group via lithiation and subsequent silylation, formylation via lithiation and successive quenching by dimethylformamide, and deprotection by a trifluoroacetic acid treatment.
- 1997-09-23
著者
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Sato Masashi
Department of Applied Biological Science, Kagawa University
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Mori N
Lab. Of Plant Genetics Graduate School Of Agricultural Sci. Kobe Univ.
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Mori Naoki
Div. Of Applied Life Sciences Graduate School Of Agriculture Kyoto Univ.
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MORI Naoki
Pesticide Research Institute, Faculty of Agriculture, Kyoto University
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Kuwahara Yasumasa
Laboratory Of Chemical Ecology Graduate School Of Agriculture Kyoto University
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Mori N
Laboratory Of Plant Genetics Department Of Biological And Environmental Science Graduate School Of A
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Kuwahara Yasumasa
Pesticide Research Institute Faculty Of Agriculture Kyoto University
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Noguchi Satoshi
Konan Agricultural High School
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NOGUCHI Satoshi
Pesticide Research Institute, Faculty of Agriculture, Kyoto University
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Mori Naoki
Division Of Applied Life Sciences Graduate School Of Agriculture Kyoto University
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Mori Naoki
Pesticide Research Institute Faculty Of Agriculture Kyoto University
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Sato Masashi
Department Of Applied Biological Science Kagawa University
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Sato Masashi
Department Of Bioresource Science Faculty Of Agriculture Kagawa University
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Kuwahara Yasumasa
Pesticide Research Institute College Of Agriculture Kyoto University
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Mori Naoki
Laboratory Of Plant Genetics Department Of Agrobioscience Graduate School Of Agricultural Science Kobe University
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