Easy Preparation Method for 2-Thioxopyrrolidine Derivatives Including 3-Hydroxy-methylene-2-thioxopyrrolidine, an Antimicrobial Degradation Product of Radish Pungent Principle, via (E,Z)-4-Methoxy-3-butenyl Isothiocyanate

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概要

• 論文の詳細を見る

• An easy preparation method was developed for 3-hydroxy-methylene-2-thioxopyrrolidine (TPC), an antimicrobial degradation product of radish pungent principle. The key intermediate, 4-methoxy-3-butenyl isothiocyanate (MBI), which was prepared from 3-cyanopropionaldehyde dimethyl acetal in 3 reaction steps, was easily converted to TPC in acidic (pH 3.0-4.0) aqueous media. In methanol or ethanol with a few drops of acetic acid, MBI afforded corresponding 3-(α,α-dialkoxy)methyl-2-thioxoprrolidines as the major products.

• 社団法人日本農芸化学会の論文
• 1996-05-23

著者

• YONEYAMA Koichi

  Weed Sci. Center, Utsunomiya Univ

• MATSUOKA Hiroki

  Department of Electronic Engineering, Tohoku University

• Matsuoka H

  Department Of Health And Nutrition Takasaki University Of Health And Welfare

• Yoneyama Koichi

  Weed Sci. Center Utsunomiya Univ.

• Yoneyama Koichi

  Weed Science Center Utsunomiya University

• UDA Yasushi

  Department of Bioproductive Sciences, Utsunomiya University

• Uda Yasushi

  Department Of Bioproductive Sciences Faculty Of Agriculture Utsunomiya University

• Uda Y

  Niigata Coll. Niigata Jpn

• Uda Yasushi

  Department Of Agricultural Chemistry Utsunomiya University

• Matsuoka Hiroki

  Department Of Biochemistry And Molecular Biology Nippon Medical School

• MITANI Kazunori

  Department of Bioproductive Science, Faculty of Agriculture, Utsunomiya University

• MAEDA Yasuhiko

  Department of Bioproductive Science, Faculty of Agriculture, Utsunomiya University

• Maeda Y

  Iwaki Meisei Univ. Fukushima Jpn

• Mitani Kazunori

  Department Of Bioproductive Science Faculty Of Agriculture Utsunomiya University

• MAEDA Yasuhiko

  Department of Agricultural Chemistry, Utsunomiya University

• YONEYAMA Koichi

  Weed Control Research Institute, Faculty of Agriculture, Utsunomiya University

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