Synthesis of 2-(2-Hydroxyalkylidene)cyclopentanones and Their Bio-antimutagenic Activity
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概要
- 論文の詳細を見る
2-(2-Hydroxyalkylidene)cyclopentanones (1) and 5-(2-hydroxyoctylidene)-2-cyclopentenone (2) were synthesized by the aldol reaction of cyclopentanone-enolate (3)/cyclopentenone-enolate (19) with 2-bromoalkanals (4)/2-bromooctanal (4c) and subsequent treatment of the products with sodium acetate. The stereochemistry of the condensation, substitution and elimination was elucidated. The bio-antimutagenic activity of 1 increased as the 2-hydroxyalkylidene group increased in length up to =CHCH(OH)C_8H_<17>.
- 社団法人日本農芸化学会の論文
- 1995-03-23
著者
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NAKAMURA Atsushi
Department of Medical Oncology and Immunology, Nagoya City University Graduate School of Medical Sci
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IRIYE Ryozo
Department ofBioscience and Biotechnology, Faculty of Agriculture, Shinshu University
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Iriye R
Shinshu Univ. Nagano Jpn
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Nakamura Atsushi
Department Of Applied Physics Fukuoka University
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Iriye Ryozo
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Mie
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Takeshita Masahiko
Department of Bioscience and Biotechnology, Faculty of Agriculture, Shinshu University
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Takeshita Masahiko
Department Of Bioscience And Biotechnology Faculty Of Agriculture Shinshu University
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Nakamura Atsushi
Department Of Applied Physics Faculty Of Science Fukuoka University
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IRIYE Ryozo
Department of Agricaltural Chemistry, Faculty of Agriculture, Shinshu University
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