Stage Stability and Stage Transformation of SbCl_5-Graphite Intercalation Compounds

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概要

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• Stage stability and stage transition in SbCl,-graplaite intercalation compounds havebeen investigated by use of the in situ X-ray diffraction technique. A precise isothermof stage n has been determined for stages up to 6. The stage-stability range in chemi-cat potential Ap(n) is evaluated from the isotherm. A comparison of Ay(n) with thetheoretical results of the electrostatic interlayer interaction motiel gives the ionicity ofI /4<f< l /2 for SbCl,-graphite intercalation compounds. A very narrow two-phaseregion is observed in the stage transition region, in which two single-stage phases coex-ist in thermal equilibrium.

• 社団法人日本物理学会の論文
• 1986-02-15

著者

• SATO Kiyoo

  Department of Physics, Faculty of Engineering, Yokohama National University

• Sato Kiyoo

  Department Of Physics Faculty Of Science Toyama University

• Sato Kiyoo

  Department Of Physics College Of Liberal Arts Toyama University

• SUEMATSU Hiroyoshi

  Institute of Materials Science,University of Tsukuba

• Suematsu Hiroyoshi

  Institute For Solid State Physics University Of Tokyo:university Of Tsukuba Institute Of Material Sc

• SUDA Kei

  Institute of Materials Science,University of Tsukuba

• Suda K

  Institute Of Materials Science University Of Tsukuba

• Suda Kei

  Institute Of Materials Science University Of Tsukuba

• YOSIDA Yositaka

  Department of Physics,Faculty of Science,Toyama University

• Yosida Yositaka

  Department Of Material Science College Of Science And Engineering Iwaki-meisei University

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