On the Superstructure of the Ordered Alloy Cu_3Pd : II. X-ray Diffraction Study
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概要
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The structures of the ordered copper-palladium alloys in the composition range from 15.5 to 28.5 atomic per cent Pd were investigated by X-ray diffraction, using both single crystals and power specimens. The alloys with the composition of 20.8 to 25.8 atomic per cent Pd have an anti-phase domain structure in a fully ordered state cooled slowly from 450℃ to room temperature in four months. This structure is formed from the elementary face-centered tetragonal lattice, in which the atoms arrange themselves as in the ordered alloy Cu_3Au but step-shifts occur at a definite period along the tetragonal axis. On the other hand, the alloys of 27.3 and 28.5 atomic per cent Pd were confirmed to possess a more complicated anti-phase domain structure characterized by the two kinds of out-of-step, which was already elucidated by the electron diffraction study in Part I. Variation of both the lattice parameters and the periods of anti-phase domain with composition were also studied.
- 社団法人日本物理学会の論文
- 1957-03-05
著者
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Ogawa Shiro
The Rcsearch Institute For Iron Steel And Other Metals Tohoku University
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Hirabayashi Makoto
The Research Institute For Iron Steel And Other Metals
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