<Original>The C_α-C_β Bond Cleavage of the Secondary Metabolite Veratryglycerol Catalized by A New Modified "Ligninase" Preparation from Phanerochaete chrysosporium
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概要
- 論文の詳細を見る
この論文は国立情報学研究所の学術雑誌公開支援事業により電子化されました。The various culture conditions for production of lignin peroxidase were examined by use of the white-rot fungus Phanerochaete chrysosporium grown for 4 days in the cultures with high carbon and low nitrogen (HC/LN)-, low carbon and high nitrogen (LC/HN)-, or low carbon and medial nitrogen (LC/MN)-media. Among them, LC/MN-culture with 0.1% Tween 80 produced the greatest amount of ligninase activity (356 units/l). A secondary metabolite veratrylglycerol occurring in the extra-cellular culture fluid underwent Cα-Cβ bond cleavage in the presence of ligninase and hydrogen peroxide, yielding veratraldehyde and glycolaldehyde. The oxidation rates of a threo- and a mixture of threo- and erythro-forms of veratrylglycerol synthesized were about 60% of that of veratryl alcohol. A possible relevance of this cleavage reaction to the Cα-Cβ bond cleavage of arylglycerol-β-aryl ether substructures of lignin polymer was discussed.
- 京都大学の論文
- 1989-12-28
著者
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Hattori Takefumi
Wood Research Institute Kyoto University
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Hattori Takefumi
Research Institute Of Sustainable Humanosphere Kyoto University
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島田 幹夫
京都大学生存圏研究所
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SHIMADA Mikio
Research Section of Lignin Chemistry, WOOD RESEARCH INSTITUTE, KYOTO UNIVERSITY
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HIGUCHI Takayoshi
Research Section of Lignin Chemistry, WOOD RESEARCH INSTITUTE, KYOTO UNIVERSITY
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KUROSAKA Hiroshi
Research Section of Lignin Chemstry, WOOD RESEARCH INSTITUTE, KYOTO UNIVERSITY
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UZURA Kensaku
Nagase Biochemicals Co. Ltd.
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Uzura Kensaku
Nagase Biochemicals Ltd.
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Kurosaka Hiroshi
Research Section Of Lignin Chemstry Wood Research Institute Kyoto University
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Higuchi T
Kyoto Univ.
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Higuchi Takayoshi
Research Section Of Lignin Chemistry Wood Research Institute Kyoto University
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Higuchi T
Soy Sauce Research Laboratory R & D Division Kikkoman Corporation:(present Address)research And
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HATTORI Takefumi
Research Institute for Sustainable Humanosphere, Kyoto University
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