First Diastereoselective Construction of Butane-Type and Butyrolactone-Type Secocyclolignane Structures
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概要
- 論文の詳細を見る
The first diastereoselective construction of butane-type and butyrolactone-type secocyclolignanes was achieved by the application of a high-valency heterobimetallic Ir–Sn complex to benzyl alcohols prepared from an Evans’s anti-aldol product. The elimination of an acetoxymethyl group to give a cinnamyl structure by using a high-valency heterobimetallic Ir–Sn complex was also observed in this study.
- 社団法人 日本農芸化学会の論文
- 2009-11-23
著者
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YAMAUCHI Satoshi
Faculty of Agriculture, Ehime University
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Yamauchi Satoshi
Faculty Of Agriculture Ehime University
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MORITA Masao
Faculty of Agriculture, Ehime University
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Morita Masao
Fac. Of Agriculture Ehime Univ.
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Morita Masao
Faculty Of Agriculture Ehime University
関連論文
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- Antimicrobial Activity of Stereoisomers of Morinols A and B, Tetrahydropyran Sesquineolignans
- Stereoselective Construction of Tetra-Substituted Tetrahydrofuran Compounds from Benzylic Hemiacetal in the Presence of H2 and a Pd Catalyst: Stereoselective Synthesis of a Stereoisomer of (−)-Virgatusin and Its Antimicrobiological Activity
- Immunostimulation Effect of Jellyfish Collagen
- Antibacterial Activity of a Virgatusin-Related Compound
- Antifungal Activity of Tetra-Substituted Tetrahydrofuran Lignan, (−)-Virgatusin, and Its Structure-Activity Relationship
- Antimicrobiological Activity of Lignan: Effect of Benzylic Oxygen and Stereochemistry of 2,3-Dibenzyl-4-butanolide and 3,4-Dibenzyltetrahydrofuran Lignans on Activity
- Effect of Benzylic Oxygen on the Cytotoxic Activity for Colon 26 Cell Line of Phenolic Lignans
- Radical and Superoxide Scavenging Activities of Matairesinol and Oxidized Matairesinol
- Absolute Configuration of Volicitin from the Regurgitant of Lepidopteran Caterpillars and Biological Activity of Volicitin-Related Compounds
- The Effect of Secoisolariciresinol on 3T3-L1 Adipocytes and the Relationship between Molecular Structure and Activity
- Mode of Action of the Immunostimulatory Effect of Collagen from Jellyfish
- Affinity to the Nicotinic Acetylcholine Receptor and Insecticidal Activity of Chiral Imidacloprid Derivatives with a Methylated Imidazolidine Ring
- Enhanced Sequence Coverage in Tryptic Fragment Analysis by Two-Dimensional HPLC/MS Using a Monolithic Silica Capillary Column
- First Stereoselective Synthesis of meso-Secoisolariciresinol and Comparison of Its Biological Activity with (+) and (−)-Secoisolariciresinol
- Immunomodulatory Effect of (−)-Matairesinol in Vivo and ex Vivo
- Inhibition of the Discoloration of Yellowtail Dark Muscle by Lignan
- IgE-Suppressive Activity of (-)-Matairesinol and Its Structure-Activity Relationship
- Antifungal Activity of Morinol B Derivatives of Tetrahydropyran Sesquilignan
- Antimicrobial Activity of Stereoisomers of Butane-Type Lignans
- Inhibition of the Discoloration of Yellowtail Dark Muscle by Lignan
- Syntheses and Antimicrobial Activity of Tetrasubstituted Tetrahydrofuran Lignan Stereoisomers
- Antimicrobial Activity of Stereoisomers of Morinols A and B, Tetrahydropyran Sesquineolignans
- The Effect of Secoisolariciresinol on 3T3-L1 Adipocytes and the Relationship between Molecular Structure and Activity
- Antioxidant Activity of Butane Type Lignans, Secoisolariciresinol, Dihydroguaiaretic Acid, and 7,7'-Oxodihydroguaiaretic Acid
- Syntheses of All Stereoisomers of Goniodiol from Yeast-Reduction Products and Their Antimicrobiological Activity
- Structure-Antibacterial Activity Relationship for 9-O,9'-O-Demethyl (+)-virgatusin
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- First Stereoselective Synthesis of meso-Secoisolariciresinol and Comparison of Its Biological Activity with (+) and (-)-Secoisolariciresinol
- Antimicrobiological Activity of Lignan : Effect of Benzylic Oxygen and Stereochemistry of 2,3-Dibenzyl-4-butanolide and 3,4-Dibenzyltetrahydrofuran Lignans on Activity
- Antifungal Activity of Tetra-Substituted Tetrahydrofuran Lignan, (-)-Virgatusin, and Its Structure-Activity Relationship
- Antibacterial Activity of a Virgatusin-Related Compound
- Syntheses of Secocyclolignanes and Comparative Antioxidative Activity between Secocyclolignane and the Dibenzyl Type of Lignan
- Synthesis of Amino Tetrahydrofuran Lignan via an N,O-Heterocyclic Compound as an Intermediate
- Synthesis of an Optically Pure Synthetic Intermediate of Aloperine from a Yeast-Reductive Product
- Synthesis and Antioxidant Activity of Olivil-Type Lignans
- Synthesis and Antioxidant Activity of Oxygenated Furofuran Lignans
- First Diastereoselective Construction of Butane-Type and Butyrolactone-Type Secocyclolignane Structures
- Improved Syntheses of Morinol C and D by Employing Mizoroki-Heck Reaction and Their Cytotoxic and Antimicrobial Activities
- Mode of Action of the Immunostimulatory Effect of Collagen from Jellyfish
- Use of the Benzyl Mesylate for the Synthesis of Tetrahydrofuran Lignan: Syntheses of 7,8-trans, 7′,8′-trans, 7,7′-cis, and 8,8′-cis-Virgatusin Stereoisomers
- Immunomodulatory Effect of (-)-Matairesinol in Vivo and ex Vivo
- Larvicidal Activity of (−)-Dihydroguaiaretic Acid Derivatives against Culex pipiens
- Effect of the Benzylic Structure of Lignan on Antioxidant Activity
- Syntheses of Secocyclolignanes and Comparative Antioxidative Activity between Secocyclolignane and the Dibenzyl Type of Lignan
- Disruption of Ion Homeostasis by Verrucosin and a Related Compound
- Synthesis of a Glandular Secretion of the Civet Cat, (2S,6S)-(6-Methyltetrahydropyran-2-yl)acetic Acid and Its Enantiomer, by Using the Yeast-Reduction Product and Recovered Substrate from Yeast Reduction
- Syntheses of (+)- and (-)-Dihydropinidine and (+)- and (-)-Epidihydropinidine by Using Yeast Reduction of Methyl (2-oxocyclohexyl)acetate
- Affinity to the Nicotinic Acetylcholine Receptor and Insecticidal Activity of Chiral Imidacloprid Derivatives with a Methylated Imidazolidine Ring
- New Method for Synthesizing the Intermediates to 5-HETE from Yeast-mediated Reduction Products by Employing Baeyer-Villiger Oxidation with Complete Retention of Enantiomeric Excess(Organic Chemistry)
- Larvicidal Activity of (-)-Dihydroguaiaretic Acid Derivatives against Culex pipiens
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