Solubilization of Calixarenes in an Aliphatic Organic Solvent by Reverse Micelles
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概要
- 論文の詳細を見る
Solubilization of a calix[4]arene carboxylic acid derivative in an aliphatic organic solvent was accomplished by utilizing a reverse micellar solution. The reverse micellar solution was prepared by cationic cetyltrimethyl ammonium bromide (CTAB) or anionic bis-2-ethylhexyl sulfosuccinate (AOT). Both reverse micellar solutions facilitate the solubilization of the calix[4]arene carboxylic acid derivative in isooctane. The concentration of calix[4]arene solubilized in the reverse micelles increases with an increase of surfactant concentration. The water content in the reverse micelles (W0 = [H2O]/[surfactant]) also affects the solubilization behavior of calix[4]arene. The optimum water content existed for the formation of the reverse micelles and the value was around 20. The extraction performance of calix[4]arene solubilized was investigated for yttrium (III) in isooctane. The extraction ability of calix[4]arene was enhanced by solubilizing in the anionic reverse micellar solution.
- 社団法人 化学工学会の論文
- 2002-10-01
著者
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GOTO Masahiro
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
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後藤 雅宏
九州大学大学院工学研究院応用化学部門
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Shinohara Kenji
Department of Medicine, Yamaguchi Prefectural Medical Center
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KUBOTA Fukiko
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
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Oshima Tatsuya
Department of Applied Chemistry, University of Miyazaki
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Oshima Tatsuya
Department Of Applied Chemistry Faculty Of Science And Engineering Saga University
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Goto Masahiro
Department Of Applied Chemistry Graduate School Of Engineering Kyushu University
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Shimojo K
Division Of Environment And Radiation Science Nuclear Science And Energy Directions Japan Atomic Ene
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Shimojo Kojiro
Department Of Applied Chemistry Graduate School Of Engineering Kyushu University
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Shinohara K
Division Of Hematology Department Of Medicine Yamaguchi Prefecture Central Hospital
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Shinohara Kenji
Division Of Hematology Department Of Medicine Yamaguchi Prefecture Central Hospital
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Shinohara Kenji
Yamaguchi Prefecture Central Hospital Hofu Jpn
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Kubota Fukiko
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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Shinohara Kenji
Department Of Biology School Of Education Waseda University
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Goto Masahiro
Department Of Applied Biological Chemistry The University Of Tokyo
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Shinohara Kenji
Department Of Applied Chemistry Graduate School Of Engineering Kyushu University
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