Metal-Imprinted Microsphere Prepared by Surface Template Polymerization with W/O/W Emulsions
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概要
- 論文の詳細を見る
A Zn(II)-imprinted microsphere is prepared by surface template polymerization with W/O/W emulsions. Dioleyl phosphoric acid, which has two long alkyl chains in the hydrophobic moiety, and divinylbenzene were employed as a functional host and a cross-linking agent, respectively. In order to create a spherical imprinted polymer, composition of the external aqueous phase in the W/O/W emulsion is a key factor: the value of the ionic strength to prevent shrinking of emulsions during polymerization and the choice of the water-soluble surfactant for stabilizing the spherical W/O emulsion are important. The metal-imprinted beads exhibit a high selectivity towards target zinc ions over copper ions. The novel preparation technique is very useful for an industrial application because it can easily control the particle size between 10 and 100 μm.
- 社団法人 化学工学会の論文
著者
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GOTO Masahiro
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
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上江洲 一也
北九大・国際環境工
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Goto M
Kyushu Univ. Fukuoka
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NAKASHIO Fumiyuki
Department of Chemical Science and Technology, Kyushu University
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古崎 新太郎
崇城大学工学部応用生命科学科
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上江洲 一也
北九州市立大学国際環境工学部環境化学プロセス工学科
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UEZU Kazuya
Department of Chemical Processes and Environments, Faculty of Environmental Engineering, The Univers
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FURUSAKI Shintaro
Department of Applied Life Science, Faculty of Engineering, Sojo University
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NAKAMURA Hiroki
Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
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Uezu Kazuya
Department Of Chemical Processes And Environments Faculty Of Environmental Engineering The Universit
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後藤 元信
熊本大学バイオエレクトリクス研
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Goto M
Department Of Applied Chemistry Kyushu University
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Furusaki Shintaro
Department Of Applied Life Science Faculty Of Engineering Sojo University
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Goto Masahiro
Department Of Applied Chemistry Graduate School Of Engineering Kyushu University
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Nakashio F
Department Of Applied Chemistry Faculty Of Engineering Sojo University
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Nakashio F
Department Of Applied Chemistry Kyushu University
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Nakashio Fumiyuki
Department Of Cemical Science & Technology Kyushu University
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Nakamura H
Yamaguchi Univ. Ube Jpn
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Goto Masahiro
Department Of Applied Biological Chemistry The University Of Tokyo
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Nakamura Hiroki
Department Of Applied Physics And Chemistry The University Of Electro-communications:(present Addres
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Nakashio Fumiyuki
Department Of Applied Chemistry Kyushu University
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