ENANTIOSELECTIVE PERMEATION OF AMINO ACID ISOMERS THROUGH L-PHENYLGLYCINE-FIXED MEMBRANES AT PRESSURE GRADIENT
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概要
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Three types of L-phenylglycine-rixed membranes were prepared by varying casting conditions. The optical resolution of racemic phenylglycine (DL-Pgly) was performed by pressure gradient. L-Pgly-fixed membranes were permeable in preference to D-Pgly to L-Pgly, and the maximum separation factors of respective membrane under the operating conditions were 9.1, 8.6 and 2.7. Apparent self-association constants were evaluated from the dialysis data. By applying these values to the basic solute flux equations at a given pressure gradient, the values of the viscous parameters were evaluated. The ratio of viscous parameter of D-Pgly to that of L-Pgly depended on the apparent self-association constant. The separation factor was successfully represented on the basis of the basic solute flux equations including the apparent self-association constants, and the separation factor became larger in denser membranes with low volume flux.
- 社団法人 化学工学会の論文
- 1994-08-20
著者
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Tone Setsuji
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
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Masawaki Teruyuki
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
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Matsumoto Satoshi
Department Of Neurological Surgery Kobe University School Of Medicine
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Matsumoto Satoshi
Department Of Agricultural Chemistry University Of Tokyo
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Matsumoto Satoshi
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
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