Face-to-Face Annealing Process of Cu2ZnSnS4 Thin Films Deposited by Spray Pyrolysis Method
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概要
- 論文の詳細を見る
Cu2ZnSnS4 thin films were deposited by the spray pyrolysis method. Copper(II) acetate monohydrate, zinc(II) acetate dihydrate, tin(II) chloride dihydrate, sodium trihydrate, and pure sulfur powder were used as the starting materials of spray pyrolysis solutions, and N,N-dimethylformamide and monoethanolamine were used as the solvent and the stabilizer, respectively. The solution was coated on a Mo-coated soda lime glass substrate and after coating solutions, the films were annealed in a N2 gas atmosphere at 360, 440, and 520 °C with or without placing two films face-to-face. It was found that the face-to-face annealing process prevented losses of S and Sn during the annealing process and the samples annealed with another precursor placed face-to-face at 440 and 520 °C showed narrow and large X-ray diffraction peaks and large grains in the surface images.
- 2012-10-25
著者
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Uchiki Hisao
Department Of Electrical Engineering Nagaoka University Of Technology
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Tanaka Kunihiko
Department Of Astrophysics Nagoya University
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Goto Koichi
Department Of Information And Computer Science Faculty Of Engineering Kagoshima University
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Nakano Yuya
Department Of Pediatrics Showa University School Of Medicine
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Kato Minoru
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Kato Minoru
Department of Electrical Engineering, Nagaoka University of Technology, Nagaoka, Niigata 940-2188, Japan
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Goto Koichi
Department of Electrical Engineering, Nagaoka University of Technology, Nagaoka, Niigata 940-2188, Japan
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Nakano Yuya
Department of Electrical Engineering, Nagaoka University of Technology, Nagaoka, Niigata 940-2188, Japan
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