Transformation between Monovalent and Divalent Ionic Solids : An Ionic(I)-Ionic(II) Phase Transition in a Biferrocene-F_1TCNQ Charge-Transfer Complex(Cross-disciplinary Physics and Related Areas of Science and Technology)
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概要
- 論文の詳細を見る
An "ionic(I)-ionic(II)" charge-transfer transition has been observed in a new molecular solid composed of dineopentylbiferrocene (D) and fluorotetracyanoquinodimethane (A). The material is a monovalent solid (D^+A_3^-) at room temperature and changes to a divalent solid (D^<2+>A_3^<2->) at low temperatures, in association with a broad first-order phase transition at around 120K.
- 2005-08-15
著者
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Nishio Yutaka
Department Of Chemistry Faculty Of Science Toho University
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Kajita Koji
Department Of Physics Faculty Of Science Toho University
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Takeda Masuo
Department Of Chemistry Faculty Of Science Toho University
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Mori Hatsumi
Institute For Solid State Physics The University Of Tokyo
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Mochida Tomoyuki
Department Of Chemistry Faculty Of Science Toho University
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TAKAZAWA Kousuke
Department of Chemistry, Faculty of Science, Toho University
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Sugawara Tadashi
Department Of Basic Science Graduate School Of Arts & Sciences The University Of Tokyo
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Takahashi Masashi
Department Of Animal And Grassland Research National Agricultural Center For Kyushu Okinawa Region
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Sato Michiko
Department Of Biotechnology Tokyo University Of Agriculture And Technology
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MATSUSHITA Michio
Department of Applied Chemistry, Graduate School of Engineering, Tokyo Metropolian University
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