Adsorption of alkaline earth cations on mercury as studied with the perbromate kinetic probe.
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概要
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Reduction of perbromate was used as a kinetic probe of double layer parameters for weak specific adsorption of double layer parameters for weak specific adsorption of alkaline earth cations at the mercury/electrolyte solutions interface. The results are interpreted as evidence for weak specific adsorption of Sr<SUP>2+</SUP> and particularly Ba<SUP>2+</SUP> in 10 mM solutions at negative electrode charge densities. The limitation of the use of an anionic probe for the quantitation of cation specific adsorption is discussed.
- 公益社団法人 日本化学会の論文
著者
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Osaka Tetsuya
Department Of Applied Chemistry Faculty Of Science And Engineering Waseda University
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Osaka Tetsuya
Department of Chemistry, Georgetown University
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de Levie
Department of Chemistry, Georgetown University
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