A new synthetic route to electrophilic cyclopropane derivatives from olefins.

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概要

• 論文の詳細を見る

• 1,1-Bis(alkoxycarbonyl)-, 1-alkoxycarbonyl-1-cyano-, and 1,1-dicyanocyclopropane derivatives were obtained in 10–99% yields by the reaction of Br<SUB>2</SUB>C(COOR)<SUB>2</SUB>, Br<SUB>2</SUB>C(CN)(COOR), and KBr[Br<SUB>2</SUB>C(CN)<SUB>2</SUB>]<SUB>4</SUB>, respectively, with olefins and Cu<SUB>2</SUB>Br<SUB>2</SUB> in dimethyl sulfoxide (DMSO).

• 公益社団法人 日本化学会の論文

著者

• Hashimoto Jiro

  Department Of Urology Sapporo Medical University School Of Medicine

• Yoshida Jun-ichi

  Department Of Biological Science Faculty Of Science Kumamoto University

• Kawabata Nariyoshi

  Department Of Chemistry And Materials Technology Faculty Of Engineering And Design Kyoto Institute O

• Yano Shinji

  Department of Chemistry, Faculty of Polytechnic Science, Kyoto Institute of Technology

• Hashimoto Jiro

  Department of Chemistry, Faculty of Polytechnic Science, Kyoto Institute of Technology

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