Polycondensation of Malononitrile and Methylenedimalononitrile with Bis(chloromethyl)Aromatic Compounds Using Triethylamine as Acid Acceptor
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概要
- 論文の詳細を見る
Malononitrile was found to undergo condensation reaction with benzyl chloride to give dibenzylmalononitrile in a quantitative yield under mild conditions when an organic base such as triethylamine was used as acid acceptor in dimethyl sulfoxide. The reaction was applied to the polycondensation of malononitrile and methylenedimalononitrile with <I>p</I>-xylylene dichloride and <I>p</I>,<I>p</I>′-bis(chloromethyl)diphenyl ether, polymers with intrinsic viscosity 0.14–0.22 dl/g being obtained in quantitative yields.
- 公益社団法人 日本化学会の論文
著者
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Kawabata Nariyoshi
Department Of Chemistry And Materials Technology Faculty Of Engineering And Design Kyoto Institute O
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MATSUBARA KENICHI
Department of Biochemistry, Kyushu University
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Yamashita Shinzo
Department of Material Science, Kyoto Institute of Technology
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Matsubara Kenichi
Department of Chemistry, Kyoto Institute of Technology
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