Stereoselectivity of Phenylcarbenoid of Zinc in Cycloaddition with Olefin
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概要
- 論文の詳細を見る
The stereoselectivity of phenylcarbenoid of zinc generated from diethylzinc and benzal iodide was investigated in the cycloaddition reaction with olefin. The carbenoid showed larger <I>syn</I>-selectivity than phenylcarbenoid of lithium. Electron-donating substituent attached to the phenyl group of the phenylcarbenoid enhanced the <I>syn</I>-selectivity of the carbenoid. The <I>syn</I>-selectivity of the phenylcarbenoid was larger in ether than in <I>n</I>-pentane, contrary to the case of phenylcarbenoid of lithium.
- 公益社団法人 日本化学会の論文
著者
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Furukawa Junji
Department Of Applied Chemistry Aichi Institute Of Technology
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Kawabata Nariyoshi
Department Of Chemistry And Materials Technology Faculty Of Engineering And Design Kyoto Institute O
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Nishimura Jun
Department Of Chemistry And Chemical Biology Graduate School Of Engineering Gunma University
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Koyama Hiroaki
Department of Synthetic Chemistry, Kyoto University
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