A wittig-type reaction of phosphoranes with carbon monoxide coordinated to palladium. A synthetic route to isocyanide palladium complexes.
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概要
- 論文の詳細を見る
The reaction of carbon monoxide with triphenyl(phenylimino)phosphorane proceeded at room temperature in the coordination sphere of palladium to give a mixture of phenyl isocyanide and carbonyl complexes of palladium. Triphenyl (<I>t</I>-butylimino)phosphorane gave bis(<I>t</I>-butyl isocyanide)palladium chloride in a low yield. Benzophenone triphenylphosphazine and triphenyl(<I>p</I>-tolylsulfonylimino)phosphorane failed to react with carbon monoxide.
- 公益社団法人 日本化学会の論文
著者
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Okazaki Satoshi
Department Of Applied Chemistry Kyushu Institute Of Technology
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Furukawa Junji
Department Of Applied Chemistry Aichi Institute Of Technology
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MATSUMURA Akira
Department of Electronic Science and Engineering, Faculty of Engineering, Kyoto University
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Kiji Jitsuo
Department of Chemistry Faculty of Science Osaka University
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Okazaki Satoshi
Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University
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Haishi Tomoyuki
Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University
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