ACID-BASE EQUILIBRIA IN ACETYLACETONE: DISSOCIATION OF SOME WEAK ACIDS AND THE AUTOPROTOLYSIS CONSTANT OF THE SOLVENT
スポンサーリンク
概要
- 論文の詳細を見る
The dissociation and horaoconjugation constants of 2,5-dichlorobenzenesulfonic, p-toluenesulfonic, methanesulfonic and picric acids have been determined at 25℃ in acetylacetone by conductometry and potentiometry, and compared with those in other solvents. The autoprotolysis constant (K_S) of acetylacetone was estimated potentiometrically with a glass electrode (pK_S = 19.3).
- 社団法人日本分析化学会の論文
- 1982-01-05
著者
-
Okazaki Satoshi
Department Of Applied Chemistry Kyushu Institute Of Technology
-
Fujinaga Taitiro
Department Of Chemistry Faculty Of Science Kyoto University
-
Okazaki Satoshi
Department Of Chemistry Faculty Of Science Kyoto University
-
Masuda Kaoru
Department Of Chemistry Faculty Of Science Kyoto University
-
SAKAMOTO Ikko
Department of Chemistry, Faculty of Science, Kyoto University
-
Sakamoto Ikko
Department Of Chemistry Faculty Of Science Kyoto University
関連論文
- ナノ集積型微小電極を用いたペリレン二量体カチオンラジカル過塩素酸塩の析出過程およびその電気化学的発光反応の解析
- Near Field Stimulated Time of Flight Mass Surface Analyzer
- Stability and Telomere Structure of Chromosomal Fragments in Two Different Mosaic Strains of the Silkworm, Bombyx mori.(Genetics)
- Separation of Solid Particles by Density Difference in a Liquid-Solid Fluidized Bed
- Retention Characteristics in Supercritical Fluid Chromatography and Comparison with Gas Chromatography
- ACID-BASE EQUILIBRIA IN ACETYLACETONE: DISSOCIATION OF SOME WEAK ACIDS AND THE AUTOPROTOLYSIS CONSTANT OF THE SOLVENT
- Electron Spin Resonance Spectra of Nitrophenol Anion Radicals
- Kinetic studies on the reactions of electrogenerated 9,10-diphenylanthracene cation radical with water and alcohols by means of column-electrolytic stopped-flow method.
- Polarographic Investigation of Dissolved Oxygen in Nonaqueous Solvent
- Polarographic Reductions of Some Alkali and Alkaline Earth Metal Ions in Dimethylacetamide. Effect of Cation of the Supporting Electrolyte
- The polarographic reduction of various ammonium cations in hexamethylphosphoric triamide.
- Polarographic determination of bismuth, copper, iron(III), palladium, and uranium(VI) after extraction into molten naphthalene with oxine.
- Resonance Raman spectroscopic studies of electrogenerated cation radicals by column-electrolytic continuous-flow method.
- Direct determination of hyperfine coupling constants from complex and poorly resolved ESR spectra with numerical decoupling analysis.
- On the enhancement of the selectivity of organic sulfonate ion electrode by alkylphenols.
- Studies of lead-complex formation in sea water by anodic stripping methods.
- Ion pair formation between electro-generated 1,2-naphtoquinone anion radicals and alkali metal cations in acetonitrile.
- Electrochemical reduction of elemental sulfur in acetonitrile.
- Effect of molecular size on the association of p-quinone anion and lithium ion in N,N-dimethylformamide.
- A wittig-type reaction of phosphoranes with carbon monoxide coordinated to palladium. A synthetic route to isocyanide palladium complexes.
- An evaluation of ion-exchange membrane electrodes.
- Polarographic Investigation of Alkali Metal Ions in Hexamethylphosphoramide
- Synergistic effect of nitrogen neutral bases in the solvent extraction of zinc(II) and cadmium(II) diphenylcarbazonates.
- Preparation and analytical evaluation of liquid membrane electrodes based on solid-solvents.