Infrared study of 12-molybdophosphoric acid reduced by organic compounds.
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概要
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Reaction of 12-molybdophosphoric acid with ethyl methyl ketone, crotonaldehyde, methacrylaldehyde, 1-butene, or 1,3-butadiene is enhanced by the presence of water, and leads to preferential decrease in ν(P–O) at 1060 cm<SUP>−1</SUP> with preference over that in ν(Mo–O–Mo) at 880 cm<SUP>−1</SUP>, while the reaction with methanol is not dependent on the presence of water and results in rapid disappearance of ν(Mo–O–Mo) and retention of ν(P–O).
- 公益社団法人 日本化学会の論文
著者
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Maruya Ken-ichi
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Ai Mamoru
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Ai Mamoru
Research Laboratory of Resources Utilization, Tokyo Institute of Technology 4259
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Tsai Tian-hsi
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Ozaki Atsumu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology 4259
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Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
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Tsai Tian-hsi
Research Laboratory of Resources Utilization, Tokyo Institute of Technology 4259
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