Effect of Base on Palladium-Black Catalyzed Carbonylation of Iodobenzene
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概要
- 論文の詳細を見る
It was found that palladium-black is a highly active catalyst for the carbonylation of iodobenzene with carbon monoxide and methanol in the presence of potassium acetate, triethylamine, or tributylamine to give methyl benzoate. The kinetic study of the carbonylation showed that the oxidative addition of iodobenzene to a palladium(0) complex is rate-determining, and that the bases affect considerably the rate-determining step.
- 公益社団法人 日本化学会の論文
著者
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Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
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Ito Takeshi
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Mori Kunio
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Mizoroki Tsutomu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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