Dimerization and Isotopic Mixing of Ethylene by a Palladium Complex Catalyst
スポンサーリンク
概要
- 論文の詳細を見る
Dimerization and accompanied isotopic exchange of ethylene were studied with dichlorobis(benzonitrile)-palladium(II) complex in benzene solution. Dimerization as well as isotopic exchange take place simultaneously after an induction period, the extent of which is reduced by the presence of hydrogen releasing olefin such as 3-methyl-1-butene. Kinetics of dimerization is of first order in ethylene, but the dimerization rate does not immediately respond to the change in ethylene pressure. The results are interpreted in terms of a preformed palladium hydride complex.
- 公益社団法人 日本化学会の論文
著者
-
Maruya Ken-ichi
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
-
Moro-oka Yoshihiko
Research Laboratory Of Resource Utilization Tokyo Institute Of Technology
-
Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
-
Kitamura Taketsugu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
関連論文
- Dependence of Catalytic Activity in CO Hydrogenation on Strong Basic Sites of ZrO_2 Surface
- Selective Isobutene Formation in the CO Hydrogenation over Cs-doped ZrO_2
- IR Characterization of Mesoporous Tantalum Oxide, Ta-TMS-1
- Linear Relationship of the Rate of Isobutene Formation from CO and H_2 on ZrO_2 to the Monoclinic Phase Fraction
- Selective Formation of Acetic Acid from Syngas in the Presence of H_2O over Zirconium Hydroxide
- Formation of Novel Trinuclear Ruthenium Alkoxo Complexes and a Tetrameric Ruthenium Hydroxo Complex. Crystal Structure of 〔η^5-C_5Me_5)Ru〕_3(μ_3-O)(μ_3-O^iPr) and 〔η^5-C_5Me^5)Ru(μ_3-OH)〕_4
- Oxidative Dehydrogenation of Propane to Propene over Cobalt Molybdate Catalysts
- Two-Coordinate Gold(I)Aliphatic Thiolate Complex:The Au-S Distance Is Smaller than the Ag-S One
- Mononuclear Copper(II) Hydroxo Comples: Structural Effect of a 3-Position of Tris(pyrazolyl)borates
- Oxygenation of Saturated Hydrocarbyl Groups in the Dinuclear Ni(III) Bis(μ-oxo) Complexes with the Hydrotris(pyrazolyl)borate Ligands Tp^R(R=Me_3 and Pr^i_2)
- A Transition Metal-Hydroperoxo Complex Stabilized by Hydrogen-Bonding Interaction:The First Example of a Hydroperoxopalladium Species Characterized by X-Ray Crystallography, (κ^2-Tp^)Pd(PPh_3)(OOH)[Tp^=hydrotris(3, 5-diisopropylpyrazolyl)borato]
- Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3, 5-Pr^i_2pz)_3)(Ar=C_6H_4-4-F, 2, 6-Me_2C_6H_3, 6-Bu^t_2C_6H_3)
- Dimanganese Complexes Bridged with a(μ-X)(μ-Carboxylato)Unit as Models for the Active Site of Manganese Catalase(X=OH, O or (O)_2)
- Stable and Active AlPO_4 Catalyst for Decomposition of CCl_2F_2
- Novel Catalysts Effective for Dehydrofluorination of CF_3CH_3(HFC143a)into CF_2CH_2
- A Monomeric Zinc Complex Ligated by an Unsymmetric Hydrotris (pyrazolyl) borate Containing an OH Group
- X-Ray Structures of Chiral (Salen) manganese (III) Complexes : Proof of Pliability of the Salen Ligand
- A Superoxodicopper(II)Complex Oxidatively Generated by a Reaction of Di-μ-hydroxodicopper(II)Complex with Hydrogen Peroxide
- Synthesis and Characterization of Monomeric (Aryloxo)iron Complexes : [Fe^L(OAr)] and [Fe^L(OAr)_2] {L=BH(3,5-Pr^i_2pz)_3^-}
- Structure and Reactivity of C2 Species on Polymetallic Systems^
- H2 evolution from various aqueous solutions over thermally reduced TiO2 and Pt-TiO2 powder.
- The photocatalytic activity of a platinized titanium dioxide catalyst supported over silica.
- Catalytic conversion of allylic esters to corresponding allylic silanes with hexamethyldisilane and palladium(0) or rhodium(I) complexes.
- The selective liquid-phase oxidation of 3,4,5-trimethoxytoluene to 3,4,5-trimethoxybenzaldehyde.
- Crystal structures of (1,5-cyclooctadiene)di-.MU.-methoxo-dirhodium(I) and tetrakis(.ETA.3-allyl)di-.MU.-hydroxo-dirhodium(III).
- Dimerization and Isotopic Mixing of Ethylene by a Palladium Complex Catalyst
- The liquid-phase oxidation of p-methoxytoluene to p-anisaldehyde with Co(OAc)2/Ce(OAc)3/Cr(OAc)3 catalyst.
- Production of furan by vapor-phase oxidation of crotonaldehyde using heteropoly compounds as catalysts.
- Infrared study of 12-molybdophosphoric acid reduced by organic compounds.
- Improvement of acetone yield in the oxidation of propylene.
- Effect of Base on Palladium-Black Catalyzed Carbonylation of Iodobenzene
- Behavior of amine in rhodium complex-tertiary amine catalyst system active for hydrogenation of aldehyde under oxo reaction conditions.
- A study of the ligand exchange of bromo(o-tolyl)bis(triphenyl-phosphine)nickel(II) with amine by means of 31P- and 13C-NMR spectroscopy.
- Rhodium complex catalyzed hydrogenation of .ALPHA.,.BETA.-unsaturated aldehydes to unsaturated alcohols.
- A Platinum Complex Bound to Iodinated Polystyrene by a Platinum-Carbon σ-Bond
- The effect of a solvent on the carbonylation of methanol catalyzed by rhodium complexes in the presence of methyl iodide.
- Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
- Arylation of Olefin with Iodobenzene Catalyzed by Palladium
- Role of amine in arylation of ethylene with iodobenzene catalyzed by rhodium trichloride.
- Codimerization of Butadiene and Ethylene Catalyzed by σ-Arylnickel(II) Compound in the Presence of Boron Trifluoride Etherate
- Effect of additives on selective formation of isobutene from the CO-H2 reaction over ZrO2.
- Codimerization of Ethylene and Styrene Catalyzed by Bis(triphenylphosphine)σ-Arylnickel(II) Halide–Trifluoroboron Etherate
- Photocatalytic reaction on layered Cs-Nb-Ti complex oxide.
- Dimerization of Ethylene Catalyzed by σ-Arylnickel(II) Compounds
- Dimerization of Ethylene Catalyzed by σ-Aryl Nickel Compound in the Presence of Trifluoro Boron Etherate
- Gas Chromatographic Determination of Reversible Adsorption of Hydrogen. XI. Reversible Adsorption of Hydrogen over Some Metal Oxides
- The CO-H2 reaction over ZrO2 to form isobutene selectively.
- Selective dimerization of ethylene catalyzed by halogenotris(triphenylphosphine)cobalt(I) complex-Lewis acid.
- Kinetic Studies on Olefin Epoxidation by Peroxo Molybdenum Complex (MoO(O2)2HMPT)
- 31P NMR study of active species for ethylene dimerization in .SIGMA.-aryl nickel complex-AgClO4.
- Codimerization of Ethylene and Styrene Catalyzed by Bis(triphenylphosphine)σ-aryl Nickel(II) Halide- Trifluoroboron Etherate
- Dimerization of C2D4 Catalyzed by Bis(triphenylphosphine)σ-1-naphthyl Nickel (II) Bromide
- Reaction of .MU.-peroxo complexes of palladium with alcohols, amines, and thiols.