Role of amine in arylation of ethylene with iodobenzene catalyzed by rhodium trichloride.
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概要
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Rhodium trichloride effectively catalyzes the arylation of ethylene with iodobenzene in the presence of an amine to give styrene, although neither rhodium-powder nor chlorotris(triphenylphosphine)rhodium(I) is effective. The efficacy of the amine in increasing the yield of styrene is remarkable with tertiary and secondary amines but negligible with a primary amine. The difference among these amines in their interaction with rhodium trichloride is explained by their steric hindrance based on the isolation of the Rh(III)–amine complex only with primary amine.
- 公益社団法人 日本化学会の論文
著者
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Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
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Mori Kunio
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Mizoroki Tsutomu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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