Codimerization of Butadiene and Ethylene Catalyzed by σ-Arylnickel(II) Compound in the Presence of Boron Trifluoride Etherate
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概要
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The codimerization of butadiene with ethylene was studied with use of the catalyst system consisting of bis(triphenylphosphine)σ-arylnickel(II) halide and boron trifluoride etherate in methylene dichloride. The codimerization took place readily at 15 °C under 20 kg/cm<SUP>2</SUP> to give <I>trans</I>- and <I>cis</I>-1,4-hexadiene and 3-methyl-1,4-pentadiene. A catalytic amount of water significantly enhanced the catalytic activity. The reaction path to form the codimers is discussed in terms of the variation in product distribution with time and the reaction kinetics.
- 公益社団法人 日本化学会の論文
著者
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Maruya Ken-ichi
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
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Mizoroki Tsutomu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Kawata Noboru
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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