Codimerization of Ethylene and Styrene Catalyzed by Bis(triphenylphosphine)σ-Arylnickel(II) Halide–Trifluoroboron Etherate
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概要
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The codimerization of styrene with ethylene was studied using the catalyst system composed of bis(triphenylphosphine)σ-aryl(bromo)nickel(II) and trifluoroboron etherate in methylene dichloride. The codimerization takes place readily at 0 °C under atmospheric pressure to give 3-phenyl-1-butene selectively. The reaction scheme was discussed on the basis of the product distribution during the course of reaction and its kinetics.
- 公益社団法人 日本化学会の論文
著者
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Maruya Ken-ichi
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
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Mizoroki Tsutomu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Kawata Noboru
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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