Arylation of Olefin with Iodobenzene Catalyzed by Palladium
スポンサーリンク
概要
- 論文の詳細を見る
Arylation of propylene, ethylene, styrene, and methyl acrylate with iodobenzene was found to be catalyzed by metallic palladium in methanol to give methylstyrene, styrene, <I>t</I>-stilbene, and methyl cinnamate, respectively. Their yields and selectivities increased significantly by the addition of excess potassium acetate as an acceptor of hydriodic acid formed. The course of catalytic reaction is discussed in terms of the oxidative addition of iodobenzene to a palladium complex of low oxidation state.
- 公益社団法人 日本化学会の論文
著者
-
Ozaki Atsumu
Research Laboratories of Resources Utilization, Tokyo Institute of Technology
-
Mori Kunio
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
-
Mizoroki Tsutomu
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
関連論文
- Dimerization and Isotopic Mixing of Ethylene by a Palladium Complex Catalyst
- Production of furan by vapor-phase oxidation of crotonaldehyde using heteropoly compounds as catalysts.
- Infrared study of 12-molybdophosphoric acid reduced by organic compounds.
- Improvement of acetone yield in the oxidation of propylene.
- Effect of Base on Palladium-Black Catalyzed Carbonylation of Iodobenzene
- Behavior of amine in rhodium complex-tertiary amine catalyst system active for hydrogenation of aldehyde under oxo reaction conditions.
- A study of the ligand exchange of bromo(o-tolyl)bis(triphenyl-phosphine)nickel(II) with amine by means of 31P- and 13C-NMR spectroscopy.
- Rhodium complex catalyzed hydrogenation of .ALPHA.,.BETA.-unsaturated aldehydes to unsaturated alcohols.
- A Platinum Complex Bound to Iodinated Polystyrene by a Platinum-Carbon σ-Bond
- The effect of a solvent on the carbonylation of methanol catalyzed by rhodium complexes in the presence of methyl iodide.
- Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
- Arylation of Olefin with Iodobenzene Catalyzed by Palladium
- Role of amine in arylation of ethylene with iodobenzene catalyzed by rhodium trichloride.
- Codimerization of Butadiene and Ethylene Catalyzed by σ-Arylnickel(II) Compound in the Presence of Boron Trifluoride Etherate
- Codimerization of Ethylene and Styrene Catalyzed by Bis(triphenylphosphine)σ-Arylnickel(II) Halide–Trifluoroboron Etherate
- Dimerization of Ethylene Catalyzed by σ-Arylnickel(II) Compounds
- Dimerization of Ethylene Catalyzed by σ-Aryl Nickel Compound in the Presence of Trifluoro Boron Etherate
- Gas Chromatographic Determination of Reversible Adsorption of Hydrogen. XI. Reversible Adsorption of Hydrogen over Some Metal Oxides
- Selective dimerization of ethylene catalyzed by halogenotris(triphenylphosphine)cobalt(I) complex-Lewis acid.
- Kinetic Studies on Olefin Epoxidation by Peroxo Molybdenum Complex (MoO(O2)2HMPT)
- 31P NMR study of active species for ethylene dimerization in .SIGMA.-aryl nickel complex-AgClO4.
- Codimerization of Ethylene and Styrene Catalyzed by Bis(triphenylphosphine)σ-aryl Nickel(II) Halide- Trifluoroboron Etherate
- Dimerization of C2D4 Catalyzed by Bis(triphenylphosphine)σ-1-naphthyl Nickel (II) Bromide