Reaction of .MU.-peroxo complexes of palladium with alcohols, amines, and thiols.

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概要

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• Reactions of μ-peroxo complexes of palladium with alcohols, amines, and thiols proceed at room temperature to afford hydrogen peroxide and alkoxo-, amido-, and alkylthio-bridged complexes of palladium, respectively.

• 公益社団法人 日本化学会の論文

著者

• Moro-oka Yoshihiko

  Research Laboratory Of Resource Utilization Tokyo Institute Of Technology

• Ikawa Tsuneo

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Suzuki Hiroharu

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Sugimoto Ryuichi

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Eikawa Hajime

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

関連論文

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• A Transition Metal-Hydroperoxo Complex Stabilized by Hydrogen-Bonding Interaction:The First Example of a Hydroperoxopalladium Species Characterized by X-Ray Crystallography, (κ^2-Tp^)Pd(PPh_3)(OOH)[Tp^=hydrotris(3, 5-diisopropylpyrazolyl)borato]
• Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3, 5-Pr^i_2pz)_3)(Ar=C_6H_4-4-F, 2, 6-Me_2C_6H_3, 6-Bu^t_2C_6H_3)
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• Stable and Active AlPO_4 Catalyst for Decomposition of CCl_2F_2
• Novel Catalysts Effective for Dehydrofluorination of CF_3CH_3(HFC143a)into CF_2CH_2
• A Monomeric Zinc Complex Ligated by an Unsymmetric Hydrotris (pyrazolyl) borate Containing an OH Group
• X-Ray Structures of Chiral (Salen) manganese (III) Complexes : Proof of Pliability of the Salen Ligand
• A Superoxodicopper(II)Complex Oxidatively Generated by a Reaction of Di-μ-hydroxodicopper(II)Complex with Hydrogen Peroxide
• Synthesis and Characterization of Monomeric (Aryloxo)iron Complexes : [Fe^L(OAr)] and [Fe^L(OAr)_2] {L=BH(3,5-Pr^i_2pz)_3^-}
• Structure and Reactivity of C2 Species on Polymetallic Systems^
• Dye-sensitized Photolysis of Diazonium Compounds in the Presence of Thioacetamide
• Catalytic conversion of allylic esters to corresponding allylic silanes with hexamethyldisilane and palladium(0) or rhodium(I) complexes.
• The selective liquid-phase oxidation of 3,4,5-trimethoxytoluene to 3,4,5-trimethoxybenzaldehyde.
• Crystal structures of (1,5-cyclooctadiene)di-.MU.-methoxo-dirhodium(I) and tetrakis(.ETA.3-allyl)di-.MU.-hydroxo-dirhodium(III).
• Dimerization and Isotopic Mixing of Ethylene by a Palladium Complex Catalyst
• The liquid-phase oxidation of p-methoxytoluene to p-anisaldehyde with Co(OAc)2/Ce(OAc)3/Cr(OAc)3 catalyst.
• The dye-sensitized photolysis of aryl aryldiazo sulfone.
• A photoelectrochemical study of polyacetylene, (CH)x.
• Reaction of .MU.-peroxo complexes of palladium with alcohols, amines, and thiols.

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