A Study of the Catalytic Partial Oxidation of Hydrocarbons. XVI. The Effect of the Bi<SUB>2</SUB>O<SUB>3</SUB> Content in the MoO<SUB>3</SUB>-Bi<SUB>2</SUB>O<SUB>3</SUB>-P<SUB>2</SUB>O<SUB>5</SUB> Catalysts on the Oxidation of Various Olefins, Acids, and
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概要
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The vapor-phase oxidation of various kinds of olefins, acids, aldehydes, etc. was carried out in a flow system over a series of MoO<SUB>3</SUB>–Bi<SUB>2</SUB>O<SUB>3</SUB>–P<SUB>2</SUB>O<SUB>5</SUB> catalysts with different Bi/Mo ratios (P/Mo=0.2 atomic ratio) under fixed reaction conditions, in order to elucidate how the oxidation of these compounds is affected by the Bi<SUB>2</SUB>O<SUB>3</SUB> content in the catalysts. The oxidation activity for these compounds varies in different individual manners as the Bi<SUB>2</SUB>O<SUB>3</SUB> content increases. The results were interpreted successfully on the basis of the acid-base nature of the reactant and the catalyst. Then, the relationship between the character of the partial oxidations and the nature of the catalysts was discussed.
- 公益社団法人 日本化学会の論文
著者
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Ai Mamoru
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Suzuki Sadao
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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