The decomposition of t-butyl heptafluoroperoxybutyrate in aromatic and aliphatic solvents.
スポンサーリンク
概要
- 論文の詳細を見る
Kinetical studies and products analyses of the thermal decomposition of <I>t</I>-butyl heptafluoroperoxybutyrate (TBH) in benzene, octane, nitrobenzene, pyridine, and methoxybenzene have been carried out. In benzene and octane, the decomposition appears to be entirely a radical process. In nitrobenzene and pyridine, the reactions are found to give ionic decomposition products exclusively. On the other hand, the decomposition of TBH in methoxybenzene is characteristic of mixed ionic and radical cleavages.
- 公益社団法人 日本化学会の論文
著者
-
Yoshida Masato
Department Of Cardiovascular Surgery Hyogo Brain And Heart Center At Himeji
-
KOBAYASHI Michio
Department of Chemistry and Biological Science, College of Science and Engineering, Aoyama Gakuin Un
-
Aoshima Kazuyoshi
Chemicals and Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.
-
Sawada Hideo
Chemicals and Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.
-
Hagii Hidehiko
Chemicals and Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.
関連論文
- Characterization of an Extended-Spectrum β-Lactamase from Escherichia coli Mediated by a Plasmid
- A Case of the Coronary Artery Aneurysm Including Stent Device after Percutaneous Coronary Intervention
- PJ-875 Delayed Enhancement of Cardiac Magnetic Resonance Imaging Can Predict the Response to Cardiac Resynchronization Therapy in Patients with Non-ischemic Cardiomyopathy(Heart failure, clinical(21)(M),Poster Session(Japanese),The 72nd Annual Scientific
- PJ-037 What Can Predict the Cardiac Function After Ablation in Patients with Premature Ventricular Beats And Left Ventricular Dysfunction?(Arrhythmia, therapy(23)(A),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation S
- PJ-026 The similarity of Pathology of myocardium surround SVC and myocardial sleeve of Pulmonary Vein in Atrial Fiblliation(Arrhythmia, diagnosis/Pathophysiology/EPS(12)(A),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circul
- PE-492 What Can Predict the Outcome of Patients with Heart Failure And Atrial Fibrillation ; Tachycardia Induced Or Idiopathic Dilated Cardiomyopathy?(Arrhythmia, therapy(15)(A),Poster Session(English),The 72nd Annual Scientific Meeting of the Japanese Ci
- PE-263 Efficacy and Safety of Bepridil for Atrial Fibrillation in Patients with Impaired Left Ventricular Function(Arrhythmia, therapy(13)(A),Poster Session(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- PE-198 The Effect of Cardiac Resynchronization Therapy on Right Ventricular Function(Heart failure, clinical(09)(M),Poster Session(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-029 Reverse Remodeling after Cardiac Resynchronication Therapy : Where Should We Implant Left Ventricular Lead, Base, Mid or Apex?(Arrhythmia, therapy(05)(A),Oral Presentation(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Soc
- OJ-028 Reverse Remodeling after Cardiac Resynchronization Therapy : Which Coronary Vein Shoud We Select for Left Ventricular Lead Implantation?(Arrhythmia, therapy(05)(A),Oral Presentation(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circu
- OE-379 Characterization of Vulnerable Plaques in Coronary Artery by Using Three-dimensional Spiral MRI Technique ; Comparing with the Intravascular Ultrasound Studies(MRI/MRA(01)(I),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japa
- Triple Valve Replacement Late After Tetralogy of Fallot Repair : Report of a Case
- Primary Cardiac Liposarcoma Causing Cardiac Tamponade : Report of a Case
- Inflammatory Aneurysm of the Ascending Aorta : Report of a Case
- Common hepatic artery as an inflow site for off-pump coronary artery bypass grafting
- PJ-404 Prognosis of Functional Mitral Valve Regurgitation after Aortic Valve Replacement(Valvular herat disease/Pericarditis/Cardiac tumor-3, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-349 Evaluation of Appropriate Bypass Graft Length in Coronary Artery Bypass Grafting with 64-row Multidetector Computed Tomography(CT/DSA-09, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Pulmonary Thromboendarterectomy for Chronic Pulmonary Thromboembolism in Protein C Deficiency
- Combined Stent-graft and Surgical Treatment for a Thoracoabdominal Aortic Aneurysm in a High Risk Patient
- Simultaneous Operation of Off Pump Coronary Artery Bypass and Abdominal Aortic Aneurysm Repair
- Off-pump Versus On-pump Coronary Surgery According to EuroSCORE(Cardiovascular Surgery/CABG 1 (IHD), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
- Papillary Muscle Rupture Following Acute Myocardial Infarction
- PE-177 Evaluation of Graft Patency and Anastomosis after Coronary Artery Bypass Grafting with 16-row Multislice Spiral Computed Tomography(X-ray/CT/MRI/DSA6 (I) : PE30)(Poster Session (English))
- Subepicardial Aneurysm following Ventriculotomy Closure of Ventricular Septal Rupture due to Acute Myocardial Infarction
- 1P337 高速原子間力/蛍光顕微鏡複合機に向けたスタンドアロン型高速AFMの開発(バイオエンジニアリング,第48回日本生物物理学会年会)
- Surgical Assessment of Tricuspid Valve Replacement for Severe Tricuspid Regurgitation without Stenosis
- Paramalleolar Bypass Concomitantly with Extended Endarterectomy for Limb-threatening Ischemia : A Case Report
- Repeat Tricuspid Valve Replacement for Acquired Valvular Heart Disease : Report of a Case
- Successful Surgical Treatment of an Edwards Type IIIB Right Aortic Arch Aneurysm : Report of a Case
- Surgical Results of Composite Graft Replacement of the Aortic Root Aneurysm
- Acute Left Atrial Thrombus Causing Cardiogenic Shock Following Mitral Valve Replacement : Report of a Case
- CLINICAL EXPERIENCE OF LASER APPLICATION IN THE CORONARY ARTERY DISEASE : Extracorporeal Circulation, Aortic Aneurysm : 53 Annual Scientific Meeting, Japanese Circulation Society
- PJ-053 Long Term Efficacy of Cardiac Resynchronization Therapy for Patients with Chronic Heart Failure and VentricularTachycardia(Arrhythmia, therapy-14, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-108 Electroanatomic Characterization of Macroreentrant Uncommon Atrial Tachycardia in Patients without Atriotomy(Arrhythmia, therapy-07, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-071 Primary Prevention of Cardiac Sudden Death in Patients with Hypertrophic Cardiomyopathy : Is ICD Useful?(Arrhythmia, therapy-06, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- OE-395 Reverse Remodeling of left Atrium Detected by MDCT can Predict the Long Term Efficacy of Catheter Ablation for Atrial Fibrillation(CT/DSA-02, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Convenient Synthesis of 1-Fluoroalky1-2-hydro[60]fullerene Using Fluoroalkyl Halide with Tributyltin Hydride under Radical Conditions
- One-Electron Reductive Cleavage of the C-Cl Bond of ArCF_2Cl : Convenient Route for the Synthesis of ArCF_2 Derivatives
- Reductive Conversion of Chlorodifluoromethylbenzene with Samarium(II) Diiodide
- Benzoquinone-Linked Fullerenes with a Pyrrolidine Spacer
- Z-Tribenzo[c, g, k]-1, 2, 5, 6-tetradehydro[12]annulene, a Concave π-Electron System
- Synthesis of Novel Polynuclear Iron Carbonyl Complexes Using the Reactions of Methylidenecarbenes with Fe_3(CO)_
- OE-061 Clinical Significance of Non-Culprit Chronic Total Occlusion Lesion in Patient Presenting Non-ST Elevation Acute Coronary Syndrome(Acute coronary syndrome, basic/clinical-1, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Synthesis and Properties of Tetrathiafulvalene-Substituted Ferrocenes
- Synthesis of Polyamine Alkaloids by the Condensation of a Chiral β-Lactam with a Cyclic Imino Ether.(S)-Dihydroperiphylline and Its Derivatives
- Synthesis of β-Amino Esters by the Conjugate Addition of Nitrogen Nucleophiles to α, β-Unsaturated Esters Having Chiral p-Tolylsulfinyl Groups
- Convenient Preparation of (Chlorodifluoromethyl)arenes. Useful Precursors for Aryldifluoromethyl Radicals
- PJ-529 Does the Focal Tissue Damage Detected by MRI Reflect The Altered Focal Sympathetic Nerve Activity in Dilated Cardiomyopathy ?(MRI/MRA-4, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Biocompatibility and water durability of alumina-zirconia ceramics blended with microsized HA particles
- OE-374 Cardiovascular Magnetic Resonance Can Give Us Prognostic Implication ; From the Side of Sympathetic Nerve Activity(MRI/MRA(01)(I),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OE-159 Different Pattern of Vascular Remodeling of Non-Culprit Coronary Plaque Assessed by 64-Row Multi Detector Computed Tomography(CT/DSA(01)(I),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- 1 Rescent advance in cardiac MRI : The better we visualize, the more precisely we can diagnose(Symposium 14 (SY-14) (I) New Horizon of CT, MR and PET in Diagnostic Cardiac Imaging,Special Program,The 72nd Annual Scientific Meeting of the Japanese Circulat
- Photochemical Reaction Mechanism of 2, 2'-Pyridil in Alcoholic Media
- Solid Surface Enhancement Effects on Chemiluminescence : Effects of Number of Cationic Species in Solid Media
- Observation of the Radical Anion Intermediates in the Photolyses of 4-Cyano- and 4-Nitro-azobenzene in MTHF at 77K
- Absorption and Phosphorescence Spectra of Xanthone : Dimer and Tetramer Formations at Low Temperatures
- Reconstruction of the Right Ventricular Outflow Tract with a Transannular Patch for Ventricular Tachycardia Refractory to Radiofrequency Catheter Ablation in a Patient who Underwent Tetralogy of Fallot Surgery in Childhood
- 3P-257 高速原子間力顕微鏡による探針試料間の相互作用力の検出感度の向上(バイオイメージング,第47回日本生物物理学会年会)
- Oxygenative Perfluoroalkylation of Olefinic Compounds Using Perfluoroalkyl Iodide in the Presence of Oxygen
- Asymmetric Synthesis of 4-Phenyl-1,5-diazacyclooctan-2-one Using Optically Active Vinyl Sulfoxides
- Solid Surface Enhancement Effects on Chemiliuminescence. III. Diaryloxalate as Chemiliuminescence Reagent and Inorganic Materials as Media Solids
- Solid Surface Enhancement Effects on Chemiluminescence : Influence of Cationic Species in Solid Media
- Dispersion Interaction between Fluoranthene and Benzene in Cyclohexane
- Polyvinyl Alcohol as a Useful Indicator on Iodometry: Volumetric and Spectrophotometric Studies on Iodine-PVA and Iodine-Starch Complexes
- Hydrogen Bond Formations of 1-Aminoanthracene in the Ground and Excited Electronic States with protic Solvent Molecules
- A Unified Theory of Uniaxially- and Biaxially-Stretched Film Methods: Three-Dimensional Reduced Spectra of Perylene
- Appendiceal Intussusception Due to an Appendiceal Malignant Polyp-An Association in a Patient with Peutz-Jeghers Syndrome : Report of a Case
- Electronic Transitions of Ternary Copper(II) Naphthalenediolate Complexes
- Isolation, Crystallization, and Characterization of a 16.5-kDa Protein from Fruit Bodies of a Lectin-deficient Strain of Pleurotus cornucopiae
- Purification and Properties of Lectins from a Mushroom, Pleurotus cornucopiae
- Novel Synthesis of Fluoroalkylated α,β-Unsaturated Ketones by the Oxygenative Perfluoroalkylation of α-Chlorostyrenes
- Characterization of the fish intestinal microflora with fluorescently labeled rRNA-targeted oligonucleotide probes
- Synthesis of Biaryls Using the Coupling Reaction of Diaryldimethyltins with Copper(II)Nitrate
- Multi-Tetrathiafulvalene Systems. New Donors Containing Two or Three Tetrathiafulvalene-Substituents at 1,3- and 1,3,5-Positions of Aromatic Rings
- Development of microporous self-expanding stent grafts for treating cerebral aneurysms : designing micropores to control intimal hyperplasia
- Measurements of the polarized ATR spectra for adsorbed dye layers by using a stack of thin glass plates.
- Studies on Oxosulfonium Salts. I. Preparation and Physical Properties.
- Nucleophilic displacement of bis(perfluoroalkanoyl) peroxides with perfluoroalkanoate.
- A novel method for the conversion of halide anion to the positive halogen by nitrobenzenesulfonyl peroxide. Application to oxyhalogenation of olefin.
- Photolysis of Phenylazo p-Tolyl Sulfones
- Synthesis and reaction of triaminosulfoxonium salts.
- Synthesis and reaction of diaminosulfoxonium salts.
- Regioselective para halogenation of substituted benzenes with benzeneseleninyl chloride and aluminum halide.
- Heptafluoropropylation of various substituted thiophenes with bis(heptafluorobutyryl) peroxide. Preparation of 3-heptafluoropropylthiophene.
- Reaction of benzeneseleninyl chloride with olefins in the presence of a lewis acid. A novel one step vinylic chlorination.
- Photochemical reaction of 2-aryl-1,2-benzisoselenazol-3(2H)-ones.
- Photochemical reactions of spiro(benzo(b)thiophene-2(3H), 1'-cyclopropan)-3-ones.
- Photolyses of Alkyl Sulfinates and Sulfites
- Oxidative cleavage of diselenide by m-nitrobenzenesulfonyl peroxide. Novel method for the electrophilic benzeneselenenylations of olefins and aromatic rings.
- Formation and reactions of alkoxydiaminosulfonium salts.
- Syntheses and reactions of optically active alkoxyaminosulfonium salts.
- Assignment of conjugate double bond systems produced in heated PVA film by absorption and excitation spectra.
- Optical resolution of asymmetric selenoxides by high-performance liquid chromatography using optically active column.
- Asymmetric oxidation of alkyl aryl selenides under Sharpless oxidation conditions.
- Photolyses of Diaryl α-Disulfones
- Formation of Sulfur Ylids by Catalytic Action of Dialkoxy Disulfides
- The decomposition of t-butyl heptafluoroperoxybutyrate in aromatic and aliphatic solvents.
- Reaction of azo- and azoxysulfones with transition metal complexes. 4. The reaction of arylazo aryl sulfones with carbon monoxide and nucleophiles catalyzed by the palladium(0) complex.
- Radical switch reaction. A novel reaction between two free radicals in a solvent cage.
- An estimation of the configurational stability of diaryl selenoxides by means of 77Se NMR spectroscopy.