Photochemical reaction of 2-aryl-1,2-benzisoselenazol-3(2H)-ones.
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概要
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The photochemical reaction of 2-aryl-1,2-benzisoselenazol-3(2<I>H</I>)-ones (<B>1</B>) in benzene was found to give dibenzo[<I>b</I>,<I>f</I>][1,4]selenazepin-11(10<I>H</I>)-ones (<B>2</B>). On the other hand, the photochemical reaction of <B>1</B> in <I>t</I>-butyl alcohol afforded 2-(2-hydroxy-2-methylpropylseleno)benzanilide, 2-(methylseleno)benzanilide, and 2-aryl-1,2-benzisoselenazol-3(2<I>H</I>)-one 1-oxides together with the photoisomer <B>2</B>. Mechanisms for these reactions are proposed.
- 公益社団法人 日本化学会の論文
著者
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KOBAYASHI Michio
Department of Chemistry and Biological Science, College of Science and Engineering, Aoyama Gakuin Un
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Kamigata Nobumasa
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
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Izuoka Akira
Department Of Basic Science Graduate School Of Arts & Sciences The University Of Tokyo
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Iizuka Hirokazu
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Izuoka Akira
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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