Nucleophilic displacement of bis(perfluoroalkanoyl) peroxides with perfluoroalkanoate.
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概要
- 論文の詳細を見る
Bis(perfluoroalkanoyl) peroxide ((R<SUB>F</SUB>CO<SUB>2</SUB>)<SUB>2</SUB>) suffered a nucleophilic displacement with perfluoroalkanoate (R<SUB>F</SUB>′CO<SUB>2</SUB><SUP>−</SUP>) to give new mixed peroxide (R<SUB>F</SUB>(CO)OO(CO)R<SUB>F</SUB>′). When thiophene was reacted with bis(perfluoroalkanoyl) peroxide in the presence of pyridinium perfluoroalkanoate, not only the perfluoroalkyl group (R<SUB>F</SUB>) of the peroxide, but also perfluoroalkyl group (R<SUB>F</SUB>′) of perfluoroalkanoate, was introduced into thiophene.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Masato
Department Of Cardiovascular Surgery Hyogo Brain And Heart Center At Himeji
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Kamigata Nobumasa
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
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SAWADA Hideo
Tsukuba Research Laboratory, Nippon Oil & Fats Co., Ltd
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Nakayama Masaharu
Tsukuba Research Laboratory, Nippon Oil & Fats Co., Ltd.
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Sasage Shyuichi
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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