Kinetic studies on the cobalt(II) naphthenate catalyzed decomposition of "cumene hydroperoxide" in benzene.

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概要

• 論文の詳細を見る

• The cobalt(II) naphthenate[Co(Nap)<SUB>2</SUB>] catalyzed decomposition of cumene hydroperoxide(CHP) gave a mixture of α-cumyl alcohol, acetophenone and di-α-cumyl peroxide in benzene at 25°C. All experimentally observed time courses of disappearing CHP and an increasing of three products compared well with theoretical values.

• 公益社団法人 日本化学会の論文

著者

• SAWADA Hideo

  Tsukuba Research Laboratory, Nippon Oil & Fats Co., Ltd

• Nakayama Masaharu

  Tsukuba Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Ishigaki Hideyo

  Chemicals & Explosives Research Laboratory, Nippon Oil Fats Co., Ltd.

• Kato Mitsukuni

  Chemicals & Explosives Research Laboratory, Nippon Oil Fats Co., Ltd.

関連論文

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• Nucleophilic displacement of bis(perfluoroalkanoyl) peroxides with perfluoroalkanoate.
• Kinetic studies on the cobalt(II) naphthenate catalyzed decomposition of "cumene hydroperoxide" in benzene.
• Rates of thermal decomposition of t-butyl peroxypivalate.

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