Rates of thermal decomposition of t-butyl peroxypivalate.

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概要

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• The kinetics of decomposition of <I>t</I>-butyl peroxypivalate in benzene, hexane and mineral spirits were determined iodometrically in the temperature range 50–75°. The decomposition in benzene indicated smaller rate constants and activation parameters than those in hexane or mineral spirits. The solvated transition state in aromatic solvent is discussed on the basis of these results and the previously published data.

• 公益社団法人 日本化学会の論文

著者

• Ishigaki Hideyo

  Chemicals & Explosives Research Laboratory, Nippon Oil Fats Co., Ltd.

• Ishigaki Hideyo

  Chemicals and Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Komai Takeshi

  Chemical & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Matsuyama Kazuo

  Chemical & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

関連論文

• Kinetic study of the polymerization of styrene in the presence of various organic hydroperoxides.
• Kinetic studies on the cobalt(II) naphthenate catalyzed decomposition of "cumene hydroperoxide" in benzene.
• A convenient synthesis of 2-t-alkyldioxy-2-methyl-1-propanols.
• The thermal decomposition of 1-methyl-1-phenylethyl 2,2-dimethylperoxypropionate in cumene.
• Rates of thermal decomposition of t-butyl peroxypivalate.
• Synthesis and thermal decomposition of di-t-butyl peroxydicarbonate.
• Substituent effects in the decomposition of t-alkyl t-butyl peroxides.
• Thermal decomposition of 2,2-bis(t-butyldioxy)-3-methylbutane.

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