Radical switch reaction. A novel reaction between two free radicals in a solvent cage.
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概要
- 論文の詳細を見る
Studies on the thermal decomposition of <I>t</I>-butyl phenylazo sulfone suggested the occurrence of a radical switch reaction, a novel type of reaction between two radicals. A primary geminate radical pair, <I>t</I>-butanesulfonyl and phenyl radical pair, exchange sulfur dioxide to form a new radical pair consisting of <I>t</I>-butyl and benzenesulfonyl radicals. The generation of benzenesulfonyl radical was confirmed by its ESR spectrum and the isolation of products containing a benzenesulfonyl group.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Masato
Department Of Cardiovascular Surgery Hyogo Brain And Heart Center At Himeji
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KOBAYASHI Michio
Department of Chemistry and Biological Science, College of Science and Engineering, Aoyama Gakuin Un
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Gotoh Michiko
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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