SH2' Type Reactions of Arenesulfonyl Chlorides with Allylic Compounds Catalyzed by a Ruthenium(II) Complex.
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概要
- 論文の詳細を見る
In the presence of a catalytic amount of dichlorotris(triphenylphosphine)ruthenium(II), the reactions of arenesulfonyl chlorides with allyl phenyl sulfide and allyl phenyl selenide proceeded smoothly to give allyl phenyl sulfone in high yield as well as the corresponding diphenyl disulfide or diphenyl diselenide. An S<SUB>H</SUB>2′-type mechanism involving the arenesulfonyl radical is proposed.
- 公益社団法人 日本化学会の論文
著者
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Matsuyama Haruo
Department Of Applied Chemistry Faculty Of Engineering Muroran Institute Of Technology
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Kamigata Nobumasa
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
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Ohtsuka Takeshi
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Ishii Kimiko
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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