Reaction of carbon dioxide with 1-phenylaziridine catalyzed by organo-antimony and -tin compounds.
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概要
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The reactions of carbon dioxide(CO<SUB>2</SUB>) with 1-phenylaziridine(<B>1</B>) to afford 3-phenyl-2-oxazolidone(<B>2</B>) were carried out in the presence of organo-antimony and -tin compounds as catalysts. Tetraphenylstibonium bromide(Ph<SUB>4</SUB>SbBr) and triphenyltin bromide(Ph<SUB>3</SUB>SnBr) were found to be active catalysts. The use of a polar aprotic solvent, such as a HMPA, provided optimal reaction conditions.
- 公益社団法人 日本化学会の論文
著者
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Matsuda Haruo
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Hasegawa Hiroshi
Department Of Adme And Toxicology For Screening Developmental Research Laboratories Shionogi & Co. Ltd.
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Ninagawa Akira
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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