Carbonate formation from oxiranes and carbon dioxide catalyzed by organotin halide-tetraalkylphosphonium halide complexes.
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概要
- 論文の詳細を見る
Cycloaddition of carbon dioxide to oxiranes was excellently promoted by the complexes of organotin halides and tetraalkylonium halides, while either components of the complexes had no catalytic activity individually. Particularly, the complex composed of Bu<SUB>3</SUB>SnI–Bu<SUB>4</SUB>PI was the most favorable catalyst, yielding a variety of fivemembered cyclic carbonates under neutral and mild conditions.
- 公益社団法人 日本化学会の論文
著者
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Baba Akio
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Matsuda Haruo
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Nozaki Takashi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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