Reaction mechanism of cathodic crossed coupling of acetone with unsaturated compounds in acidic solution.

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概要

• 論文の詳細を見る

• It was confirmed that the cathodic crossed coupling of acetone with unsaturated compounds in aqueous sulfuric acid could proceed smoothly, when the compounds which had radical-acceptable double bonds and were adsorbed on a mercury cathode were used. From this fact, it was concluded that the coupling occurs via the addition of a radical intermediate formed by the one-electron reduction of acetone to the double bonds on the cathode surface. Possibility of the addition of an anionic intermediate derived from acetone was excluded by no occurrence of the coupling of acetone with a polar acetylenic triple bond compound adsorbed on the cathode.

• 公益社団法人 日本化学会の論文

著者

• Nonaka Tsutomu

  Department Of Electric Chemistry Tokyo Institute Of Technology

• Koizumi Toshio

  Department Of Applied Chemistry The National Defense Academy

• Fuchigami Toshio

  Department Of Electronic Chemistry Tokyo Institute Of Technology

• Sato Norio

  Department of Chemistry, Faculty of Science, Hokkaido University

• Kandeel Zaghloul

  Department of Chemistry, Faculty of Science, Cairo University

• Kandeel Zaghloul

  Department of Electronic Chemistry, Tokyo Institute of Technology

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