Stereochemical studies of the electrolytic reactions of organic compounds. IV. Electrolytic reduction of optically-active 1-pyridylalkanols to the corresponding substituted-alkyl pyridines.
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概要
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The mechanism of electrolytic reduction of 1-pyridylalkanol to the corresponding substituted-alkyl pyridine was examined by electrolyzing several optically-active 1-pyridylalkanols in an aqueous sulfuric acid solution in the vicinity of a mercury cathode. The alkyl pyridine from 1-(2-pyridyl)alkanol showed optical rotation, while that from 1-(4-pyridyl)alkanol was almost racemized.
- 公益社団法人 日本化学会の論文
著者
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Nonaka Tsutomu
Department Of Electric Chemistry Tokyo Institute Of Technology
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Fuchigami Toshio
Department Of Electronic Chemistry Tokyo Institute Of Technology
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Nonaka Tsutomu
Department of Electronic Chemistry, The Graduate School, Tokyo Institute of Technology
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Ota Tetsuro
Department of Electronic Chemistry, The Graduate School, Tokyo Institute of Technology
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