Prediction of Product-Selectivity in an Electroorganic Process by Mathematical Modeling of Reaction Mechanism. A Rotating Cylinder Electrode System.
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概要
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A mathematical mechanism model is developed for the electroreduction of carbonyl compounds in an acidic solution and shows that the formation ratio of hydrodimeric to hydromonomeric products, i.e. the product-selectivity, depends on substrate concentration, mass transfer coefficient and current density. Model calculations are in agreement with experimental results from the electroreduction of <I>p</I>-methylbenzaldehyde using a rotating cylinder cathode and explain a drastic effect of mass transport on the product-selectivity.
- 公益社団法人 日本化学会の論文
著者
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Chou Tse-chuan
Department Of Chemical Engineering College Of Engineering National Cheng Kung University
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Nonaka Tsutomu
Department Of Electric Chemistry Tokyo Institute Of Technology
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Cheng Po-chung
Department Of Electronic Chemistry Graduate School At Nagatsuta Tokyo Institute Of Technology
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Chou Tse-Chuan
Department of Chemical Engineering, National Cheng-Kung University
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