Electroorganic synthesis using organometals. 2. Reductive dehalogenation of halides with carbonylferrates derived from pentacarbonyliron(0) and cathodically-generated methoxide ion.
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概要
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A stoichiometry for the reductive dehalogenation of an organic halide with carbonylferrates was established: One mol of the halide was quantitatively reduced with the carbonylferrates derived from 0.2 mol of pentacarbonyliron(0) and 2 mol of cathodically-generated tetramethylammonium methoxide. The dehalogenation was also examined using a variety of halides under the stoichiometric reaction conditions.
- 公益社団法人 日本化学会の論文
著者
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Nonaka Tsutomu
Department Of Electric Chemistry Tokyo Institute Of Technology
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Fuchigami Toshio
Department Of Electronic Chemistry Tokyo Institute Of Technology
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Hashiba Shigeto
Department of Electronic Chemistry, Tokyo Institute of Technology
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